Pokémon - Season 11 - Eps 49: Barry's Busting Out All Over!
Upon arriving at the Hearthome Gym, Ash and his friends run into Barry, a trainer from Twinleaf Town. Barry turns out to be an admirer of Paul, whom he saw when watching the Double Battle Tournament. Ash challenges Barry to a Pokémon battle. Ash chooses Chimchar, Gliscor, and Pikachu, against Barry's Staraptor, Roserade, and Empoleon. Ash manages to narrowly defeat Barry, finishing off Empoleon with Pikachu's Volt Tackle.
About Pokémon

Title: Pokémon
First Air Date: 1997-04-01
Last Air Date: 2023-03-24
Status: Ended
Rating: 7.9/10 (from 1974 votes)
Language: JA
Seasons: 26
Total Episodes: 1235
Network: TV Tokyo TV Aichi TVQ TV Osaka TVh TSC
Genres: Animation, Action & Adventure, Sci-Fi & Fantasy
Production Companies: Shogakukan Production, TV Tokyo, OLM, Shogakukan-Shueisha Productions, SOFTX, TV Tokyo Medianet
Synopsis
Join Ash accompanied by his partner Pikachu, as he travels through many regions, meets new friends and faces new challenges on his quest to become a Pokémon Master.
Cast

Rica Matsumoto
Satoshi (voice)

Ikue Otani
Pikachu (voice)

Daiki Yamashita
Gou (voice)

Kenyu Horiuchi
Narrator (voice)